Comprehensive Organometallic Analysis

Manganese.- Organomercury Compounds.- A. Determination of Mercury.- B. Determination of Carbon, Sulphur, Halogens and Oxygen.- C. Determination of Carbon, Hydrogen and Mercury.- D. Determination of Oxygen.- Organonickel Compounds.- A. Determination of Nickel.- Organopalladium Compounds.- A. Determination of Palladium and Chloride.- Organophosphorus Compounds.- A. Determination of Phosphorus.- B. Determination of Iron, Silicon, Titanium, Arsenic and&Phosphorus.- C. Determination of Carbon and Hydrogen.- D. Determination of Nitrogen.- E. Determination of Oxygen.- F. Determination of Halogens.- G. Determination of Sulphur.- Organoplatinum Compounds.- Organopotassium Compounds.- Organoselenium Compounds.- A. Determination of Selenium.- B. Determination of Carbon and Hydrogen.- Organosilicon Compounds.- Determination of Elements.- A. Determination of Silicon.- B. Determination of Phosphorus and Silicon.- C. Determination of Aluminium and Silicon.- D. Determination of Titanium, Silicon, Phosphorus and&Aluminium.- E. Determination of Tin, Silicon and Titanium.- F. Determination of Hydrogen, Silicon and Halogen.- G. Determination of Halogens.- Determination of Functional Groups.- H. Determination of Alkoxy and Aryloxy Groups.- I. Determination of Acetoxy Groups.- J. Determination of Silicon bound Hydroxy Groups.- K. Determination of Mercaptosilanes.- L. Determination of Silidyne Groups.- M. Determination of Unsaturation.- N. Determination of Phenyl and Alkyl Groups.- O. Determination of Hydrocarbon Constituents.- P. Non-Aqueous Titrimetry.- Organothallium Compounds.- A. Determination of Carbon, Hydrogen and Thallium.- Organotin Compounds.- A. Determination of Tin.- B. Determination of Carbon and Hydrogen.- C. Determination of Halogens.- D. Determination of Nitrogen.- E. Determination of Sulphur.- Organotitanium Compounds.- A. Determination of Titanium, Iron, Phosphorus, Silicon and&Chlorine.- Organozinc Compounds.- A. Determination of Zinc.- B. Determination of Halogens.- C. Determination of Zinc-bound Alkoxy Groups.- D. Determination of Lower Alkyl and Hydride Groups.- Organozirconium Compounds.- 2 Titration Procedures.- Organoaluminium Compounds.- A. Classical Titration Procedures.- B. Conductiometric Titration.- C. Potentiometrie Titration.- D. Amperometric Titration.- E. Activity by Dielectric Constant Titration.- F. Lumometric Titration.- G. Thermometric Titration.- Organoarsenic Compounds.- Organoboron Compounds.- A. Classical Titration Procedures.- B. Potentiometrie Titration.- Organocalcium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogermanium Compounds.- Organoiron Compounds.- A. Classical Titration Procedures.- B. Potentiometrie Titration.- Organolead Compounds.- A. Classical Titration Procedures.- B. Amperometric Titration.- C. Conductiometric Titration.- D. Coulometric Titration.- E. High frequency Titration.- Organolithium Compounds.- A. Classical Titration Procedures.- B. Potentiometrie Titration.- C. Thermometric Titration.- D. High frequency Titration.- E. Lumometric Titration.- Organomagnesium Compounds.- A. Classical Titration Procedures.- B. Amperometric Titration.- C. Potentiometrie Titration.- Organomercury Compounds.- A. Classical Titration Procedures.- B. Potentiometrie Titration.- C. Coulometric Titration.- Organophosphorus Compounds.- A. Esters of Phosphoric Acid.- B. Esters of Phosphorous Acid.- C. Esters of Phosphonic, Phosphinic and Phosphorous Acids.- D. Esters of Pyrophosphoric Acid, Pyrophosphonic Acid, Phosphoroanhydrides,& Alky1-phosphonochloridates, Dialkylphosphorochloridates& and Alkylphosphonofluoridates.- E. Organophosphorus Fluoridates and Chloridates.- F. Phosphonium Salts and Phosphoranes.- G. Substituted Phosphines.- H. Trisubstituted Phosphine Oxides and Sulphides and bis&disubstituted phosphinyl Alkanes.- I. Dialkylphosphorodithioates, Dialkyldithiophosphates, Phosphorothioates,&Dialkylphosphonodithioates and other P - S&Compounds.- J. Alkyl Phosphonic.- K. Alkyl Silylphosphates&Organopotassium Compounds.- Organoselenium Compounds.- Organosodium Compounds.- Organosilicon Compounds.- A. Non-aqueous Titration.- B. Non-aqueous Conductiometric Titration.- C. Non-aqueous Amperometric Titration.- Organotin Compounds.- A. Classical Titration Procedures.- B. Potentiometrie Titration.- C. Amperometric and Coulometric Titration.- Organozinc Compounds.- A. Classical Titration Procedures.- B. Thermometric Titration.- 3 Spectroscopic Techniques, Visible And Ultraviolet Spectroscopy.- A. Visible Spectroscopy.- Organoaluminium Compounds.- Organoarsenic Compounds.- Organoboron Compounds.- Organochromium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogermanium Compounds.- Organoiron Compounds.- Organolead Compounds.- Mono-di-and Trisubstituted Lead Compounds.- Tetrasubstituted Lead Compounds.- Organomagnesium Compounds.- Organomanganese Compounds.- Organomercury Compounds.- Organonickel Compounds.- Organophosphorus Compounds.- Trialkylphosphates.- Dialkyl Hydrogen Phosphites, Trialkyl and Triaryl Phosphites.- O,0-Dialkyl-1-Hydroxyphosphonates.- Tetraethyl Pyrophosphate.- Phosphorophenoxides.- Phosphonium Salts.- Substituted Phosphine Oxides.- Alkyl Chloridates and Fluoridates and Alkylphosphoroamidocyanidate.- Dialkyldithiophosphoric Acids.- Glycerophosphates.- Organoselenium Compounds.- Organosilicon Compounds.- Organothallium Compounds.- Organotin Compounds.- Organozinc Compounds.- B. Ultraviolet Spectroscopy.- Organoboron Compounds.- Organolithium Compounds.- Organomagnesium Compounds.- Organomercury Compounds.- Organosilicon Compounds.- Organotin Compounds.- 4 Other Spectroscopic Techniques.- Organoaluminium Compounds.- A. Infrared Spectroscopy.- B. Raman Spectroscopy.- C. PMR and NMR Spectroscopy.- D. Mass Spectrometry.- Organoboron Compounds.- A. Infrared Spectroscopy.- B. NMR Spectroscopy.- C. Mass Spectrometry.- Organochromium Compounds.- Mass Spectrometry.- Organocobalt Compounds.- Infrared Spectroscopy.- Organocopper Compounds.- Mass Spectrometry.- Organogallium Compounds.- Electron probe Microanalysis.- Organogermanium Compounds.- A. Infrared Spectroscopy.- B. Mass Spectrometry.- Organoiron Compounds.- A. Infrared Spectroscopy.- B. NMR, PMR and ESR.- C. Mass Spectrometry.- D. X-Ray Diffraction and X-Ray Emission.- Organolead Compounds.- Infrared Spectroscopy.- Organolithium Compounds.- NMR Spectroscopy.- Organomanganese Compounds.- Infrared Spectroscopy.- Organomercury Compounds.- Infrared Spectroscopy.- Organonickel Compounds.- Mass Spectrometry.- Organophosphorus Compounds.- A. Infrared Spectroscopy.- B. Mass Spectrometry.- C. NMR Spectroscopy.- Organosilicon Compounds.- A. Infrared Spectroscopy.- B. Specific Functional Groups.- C. Mass Spectrometry.- D. Raman Spectroscopy.- E. NMR Spectroscopy.- Organotin Compounds.- A. Infrared and Raman Spectroscopy.- B. NMR Spectroscopy.- C. PMR Spectroscopy.- D. Mass Spectrometry.- Organozinc Compounds.- Infrared and Raman Spectroscopy.- 5 Polarographic Techniques.- Organoarsenic Compounds.- Organoboron Compounds.- Organochromium Compounds.- Organocobalt Compounds.- Organoiron Compounds.- Organolead Compounds.- Organomercury Compounds.- Organonickel Compounds.- Organophosphorus Compounds.- Organoselenium Compounds.- Organotin Compounds ,.- Organozinc Compounds.- 6 Gas Chromatography.- Organoaluminium Compounds.- Organoantimony Compounds.- Organoarsenic Compounds.- A. Alkyl and Aryl Arsines.- B. Perfluoroorganoarsenic Compounds.- C. Detectors for Organoarsenic Compounds.- D. Miscellaneous Organoarsenic Compounds.- E. Arsine.- Organoberyllium Compounds.- Organoboron Compounds.- A. Boron Alkyls.- B. Borazdes.- C. Boron Hydrides.- D. Chloroboranes.- E. Boron Halides.- F. Methyl Borate.- G. Boronates.- H. Determination of B.H. Bonding.- Organochromium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogallium Compounds.- Organogermanium Compounds.- A. Alkylgermanium Compounds.- B. Miscellaneous Organogermanium Compounds.- Organoiron Compounds.- A. Ferrocene and Derivatives.- B. Miscellaneous Organoiron Compounds.- Organolead Compounds.- Organolithium Compounds.- A. Vinyl Lithium.- B. Phenyl Lithium.- C. Methyl Lithium.- Organomagnesium Compounds.- A. Alkyl and Aryl Magnesium Halides.- B. Vinyl Magnesium Halides.- C. Etio Phorphyrin Magnesium Chelates.- Organomanganese Compounds.- Organomercury Compounds.- Organomolybdenum Compounds.- Organophosphorus Compounds.- A. Organophosphates and Thiophosphates.- B. Trialkyl and Triarylphosphites.- C. Trialkyl Phosphines, Phosphine Oxides and other oxygenated&Organophosphorus Compounds.- D. Phosphoronitrilo Halides and Phosphorus Chlorides and&Oxychlorides.- E. Insecticides and Pesticides.- Organoruthenium Compounds.- Organo selenium Compounds.- Organosilicon Compounds.- A. Silicon Hydrides.- B. Alkyl and Aryl Silanes.- C. Chlorosilanes.- D. Alkyl, Aryl and Vinyl Chlorosilanes.- E. Alkoxy Silanes.- F. Siloxanes.- G. Silyl Ethers and Silyl Thioethers.- H. Miscellaneous Organosilicon Compounds.- I. Detectors for Organosilicon Compounds.- J. Micropyrolysis-Gas Chromatography.- Organotellurium Compounds.- Organotin Compounds.- A. Alkyltin and Vinyltin Compounds.- B. Organotin Halides.- C. Organotin Oxides and Hydroxides.- Organozinc Compounds.- A. Alkylzinc Compounds.- B. Zincdialkyldithiophosphates.- 7 Chromatography of Metal Chelates.- A. Introductory.- B. Gas Chromatography, Acetyl Acetonates.- C. Gas Chromatography, Fluorinated Acetylacetonates.- D. Gas Chromatography, Hexafluoroacetylacetonates.- E. Gas Chromatography, ß-Diketone Derivatives.- F. Gas Chromatography, Amino Substituted 3-Diketonates.- G. Gas Chromatography, DialkyIdithiophosphates.- H. Gas Chromatography, Salicyaldimes.- I. Gas Chromatography, Diethyldithiocarbamates.- J. Gas Chromatography, Non-chelated Metal Complexes.- K. Gas Chromatography, Metal Porphyrins.- L. Gas Chromotographic detection of Metal Chelates.- M. Gas Chromatography, Conclusions.- N. Liquid Chromatography of Metal Chelates.- O. Size Exclusion Chromatography of Metal Chelates.- P. High performance Thin-Layer Chromatography of Metal&Chelates.- Q. Index of Metal Analysis by Gas Chromatography of their&volatile Chelates.- Illustrative examples of the application of Chromatography&to Metal Chelates.- R. Gas Chromatography.- S. High performance Liquid Chromatography.- T. Size-exclusion Chromatography.- U. High performance Thin-Layer Chromatography.- 8 Other Chromatographic Techniques.- A. Thin-layer Chromatography.- Organoantimony Compounds.- Organoarsenic Compounds.- Organobismuth Compounds.- Organoboron Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organoiron Compounds.- Organolead Compounds.- Organphosphorus Compounds.- Alkyl and Aryl Phosphates.- Alkyl and Aryl Phosphites.- Phosphonic Acids.- Phosphinic Acids.- Substituted Phosphines.- Substituted Phosphine Oxides.- Phosphorothioc Acid Esters.- Miscellaneous Organophosphorus Compounds.- Organophosphorus Insecticides and Pesticides.- Organosilicon Compounds.- Organotellurium Compounds.- Organotin Compounds.- Organozinc Compounds.- B. Paper Chromatography.- Organoarsenic Compounds.- Organobismuth Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organoiron Compounds.- Organolead Compounds.- Organomercury Compounds.- Organophosphorus Compounds.- Alkyl and Aryl Phosphates and Phosphites.- Phosphorous, Phosphinic and Phosphonic Acid Esters.- Trialkyl, Triaryl Phosphine and Phosphine Oxides.- Pyrophosphoric Acid Esters.- Phenylphosphorothioates.- Carbohydrate Esters of Phosphoric Acid.- Miscellaneous Organophosphosphorus Compounds.- Organophosphorus Insecticides and Pesticides.- Organoselenium Compounds.- Organosilicon Compounds.- Organotin Compounds.- C. Column Chromatography.- Organoarsenic Compounds.- Organocobalt Compounds.- Organoiron Compounds.- Organolead Compounds.- Organomercury Compounds.- Organonickel Compounds.- Organophosphorus Compounds.- Phosphoric Acid Esters.- Alkyl Chloridates and Fluoridates.- Carbohydrate Phosphates.- Miscellaneous Organophosphorus Compounds.- Organophosphorus Insecticides and Pesticides.- Organoselenium Compounds.- Organosilicon Compounds.- Organotin Compounds.- Organovanadium Compounds.- D. Electrophoresis.- Organoiron Compounds.- Organolead Compounds.- Organophosphorus Compounds.- Organothallium Compounds.- 9 Organometallic Compounds in the Environment.- A. Introductory.- B. Organometallic Compounds in Water.- Organomercury Compounds.- Stability of Samples.- Natural Waters.- Potable Waters.- Sea and Coastal Waters.- Sewage and Trade Effluents.- Organogermanium Compounds.- Organotin Compounds.- Organolead Compounds.- Organoarsenic Compounds.- Organoantimony Compounds.- Organocopper Compounds.- Organosilicon Compounds.- C. Organometallic Compounds in Sediments.- Organomercury Compounds.- Organotin Compounds.- Organolead Compounds.- Organoarsenic Compounds.- Organosilicon Compounds.- D. Organometallic Compounds in Plants.- Organomercury Compounds.- Organotin Compounds.- Organolead Compounds.- Organomagnesium Compounds.- E. Organometallic Compounds in Biological Materials.- Organomercury Compounds in Fish.- Organomercury Compounds in Other Biological Materials.- Organotin Compounds.- Organolead Compounds.- Organoarsenic Compounds.- Organosilicon Compounds.- F. Organometallic Compounds in Air.- Organomercury Compounds.- Organomanganese Compounds.- Organonickel Compounds.- Organotin Compounds.- Organolead Compounds.- Organosilicon Compounds.- References.