Cross-Coupling Reactions
A Practical Guide. With contrib. by S. L. Buchwald, K. Fugami, T. Hiyama et al.
(Sprache: Englisch)
This series presents critical reviews of the present position and future trends in modern chemical research. Short and concise reports on chemistry, each written by the world renowned experts. Still valid and useful after 5 or 10 years.
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This series presents critical reviews of the present position and future trends in modern chemical research. Short and concise reports on chemistry, each written by the world renowned experts. Still valid and useful after 5 or 10 years.
Klappentext zu „Cross-Coupling Reactions “
In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists donot hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of "metal-catalyzed organic syntheses". An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).
Inhaltsverzeichnis zu „Cross-Coupling Reactions “
From the contents:- K. Tamao, N. Miyaura: Introduction to Cross-Coupling Reactions
- N. Miyaura: Organoboron Compounds in Cross-Coupling Reactions
- T. Hiyama, E. Shirakawa: Organosilicon Compounds in Cross-Coupling Reactions
- K. Fugami, M. Kosugi: Organotin Compounds in Cross-Coupling Reactions
- A.R. Muci, S.L. Buchwald: Practical Palladium Catalysts for C-N and C-O Bond Formation
- M. Miura, M. Nomura: Direct Arylation via Cleavage of Activated and Unactivated C-H Bonds
Bibliographische Angaben
- Autoren: M. Kosugi , T. Hiyama , E. Shirakawa , K. Fugami , N. Miyaura , S. L. Buchwald , K. Tamao , M. Miura , M. Nomura , A. R. Muci
- 2002, 248 Seiten, Maße: 16 x 24,1 cm, Gebunden, Englisch
- Herausgegeben:Miyaura, Norio;Mitarbeit:Buchwald, S.L.; Fugami, K.; Hiyama, T.; Kosugi, M.; Miura, M.; Miyaura, N.; Muci, A.R.; Nomura, M.; Shirakawa, E.; Tamao, K.
- Herausgegeben: Norio Miyaura
- Verlag: Springer
- ISBN-10: 3540421750
- ISBN-13: 9783540421757
- Erscheinungsdatum: 11.01.2002
Sprache:
Englisch
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