Design of Electronic Devices Using Redox-Active Organic Molecules and Their Porous Coordination Networks
(Sprache: Englisch)
This book addresses the development of electronic devices using redox-active organic molecules and their porous coordination networks (PCNs), and highlights the importance of the molecular arrangement.
Redox-active organic molecules hold...
Redox-active organic molecules hold...
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This book addresses the development of electronic devices using redox-active organic molecules and their porous coordination networks (PCNs), and highlights the importance of the molecular arrangement. Redox-active organic molecules hold considerable promise as flexible electronic elements, because their electronic state can easily be controlled using external energy. Although various kinds of redox-active organic molecules have been synthesized, attempts to apply them to electronic devices have been limited, owing to the lack of proper structural design. Moreover, ligand-based redox-active PCNs remain largely unexplored because of the limited availability of redox-active ligands. In addition to developing new redox-active organic molecules, in order to design electronic devices based on these molecules/PCNs, it is essential to understand the connections between their molecular arrangement, electrical properties, and redox activity.
In this thesis, the redox-active organic molecule 2,5,8-tri(4-pyridyl)1,3-diazaphenalene (TPDAP), which features a large pi plane and multi-intermolecular interactivity, is used to develop a resistive switching memory device. In addition, its PCNs are synthesized to fabricate chemiresistive sensors, and the electrical properties are modulated using post-synthetic modification. Each mechanism is systematically investigated by means of structural determination and well-defined control experiments. Subsequently, the book proposes general guidelines for designing electronic devices using redox-active organic molecules.
The book will appeal to a broad range of readers, from basic scientists to materials engineers, as well as general, non-expert readers.
Inhaltsverzeichnis zu „Design of Electronic Devices Using Redox-Active Organic Molecules and Their Porous Coordination Networks “
1. General Introduction.- 2. Resistive Switching Memory Devices Based on a Redox-active Organic Molecule.- 3. Humidity Detection Based on Redox-active Porous Coordination Networks.- 4. Tunable Electrical Properties of Redox-active Porous Coordination Networks via Post-synthetic Modification.- 5. Summary and Outlook. Bibliographische Angaben
- Autor: Jaejun Kim
- 2022, 1st ed. 2021, XIV, 76 Seiten, 45 farbige Abbildungen, Maße: 15,5 x 23,5 cm, Kartoniert (TB), Englisch
- Verlag: Springer, Berlin
- ISBN-10: 9811639094
- ISBN-13: 9789811639098
Sprache:
Englisch
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