Modern Arylation Methods (PDF)

ARYLATION REACTIONS: A HISTORICAL PERSPECTIVE Structure and Bonding of Benzene Syntheses of Substituted (Hetero)Arenes, and the Contents of this Book METAL-CATALYZED COUPLING REACTIONS WITH ARYL CHLORIDES, TOSYLATES AND FLUORIDES Introduction Coupling Reactions of Aryl Chlorides Coupling Reactions Aryl Fluorides Coupling Reactions of Aryl Tosylates PALLADIUM-CATALYZED ARYLATIONS OF AMINES AND ALPHA-C-H ACIDIC COMPOUNDS Introduction Palladium-Catalyzed Arylations of Amines Palladium-Catalyzed Arylations of Alpha-C-H Acidic Compounds COPPER-CATALYZED ARYLATIONS OF AMINES AND ALCOHOLS WITH BORON-BASED ARYLATING REAGENTS Introduction Discovery and Development of a New O-H Bond Arylation Reaction: From Stoichiometric to Catalytic in Copper Mechanistic Considerations Miscellaneous Applications Development of a New N-H Bond Arylation Reaction Development of a New N-H Bond Arylation Reaction: Catalytic in Copper METAL-CATALYZED ARYLATIONS OF NONACTIVATED ALKYL (PSEUDO)HALIDES VIA CROSS-COUPLING REACTIONS Introduction Palladium-Catalyzed Arylations of Alkyl (Pseudo)Halides Nickel-Catalyzed Arylations of Alkyl (Pseudo)Halides Iron-Catalyzed Arylations of Alkyl (Pseudo)Halides Copper- and Cobalt-Catalyzed Arylations of Alkyl (Pseudo)Halides ARYLATION REACTIONS OF ALKYNES: THE SONOGASHIRA REACTION Introduction Palladium-Catalyzed Reactions: Ligands and Reaction Protocols Alternative Metal Catalysts Mechanism of the Sonogashira Reaction PALLADIUM-CATALYZED ARYLATION REACTIONS OF ALKENES (MIZOROKI-HECK REACTION AND RELATED PROCESSES) Introduction Mizoroki-Heck Arylations Reductive Mizoroki-Heck-Type Arylations Oxidative Mizoroki-Heck-Type Arylations MODERN ARYLATIONS OF CARBONYL COMPOUNDS Introduction Enantioselective Arylation of Aldehydes Enantioselective Arylation of Ketones Enantioselective Arylation of Imines Conjugate Asymmetric Arylation Tandem Processes Enantioselective Friedel-Crafts Arylation METAL-CATALYZED DIRECT ARYLATIONS (EXCLUDING PALLADIUM) Introduction

Lutz Ackermann was educated at the Christian-Albrechts-University Kiel, Germany, and obtained his Ph.D. in 2001 under the supervision of Alois Fürstner, Max-Plank-Institut für Kohlenforschung in Mülheim/Ruhr. He was a DAAD postdoctoral fellow in the laboratories of Robert G. Berman at the University of California at Berkeley, USA, and initiated his independent career - supported by the Emmy Noether-program (DFG) - in 2003 at the Ludwig-Maximilians-University in Munich. In 2007, he became a full professor at the Georg-August-University Göttingen. The unifying theme of his research program is represented by the development of novel concepts for efficient catalytic processes. Lutz Ackermann was visiting professor at the Università degli Studi di Milano, Italy, as well as the University of Wisconsin at Madison, USA, and his recent awards include an ORCHEM-prize, an ADUC-prize, and a Dozentenstipendium (FCI).

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