Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
(Sprache: Englisch)
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd-Ni bimetallic catalysts using density functional theory (DFT) calculations...
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Klappentext zu „Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene “
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd-Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
Inhaltsverzeichnis zu „Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene “
Introduction.- Experimental and Theoretical Methods.- Design of Pd-Ni Bimetallic Catalyst.- Effect of Oxide Supports on Pd-Ni Bimetallic Catalysts.- Replacing Precious Metals with Carbide Catalysts.- Liquid Phase Hydrogenation of Acetylene.- Conclusion.
Bibliographische Angaben
- Autor: Ruijun Hou
- 2017, 1st ed. 2017, XII, 141 Seiten, 42 farbige Abbildungen, Maße: 16 x 24,1 cm, Gebunden, Englisch
- Verlag: Springer, Berlin
- ISBN-10: 9811007721
- ISBN-13: 9789811007729
- Erscheinungsdatum: 12.01.2017
Sprache:
Englisch
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