Interfacial Electrochemistry

Metal and semiconductor electrodes.- Electrolyte solutions.- A few basic concepts.- The metal-solution interface.- Adsorption on metal electrodes: principles.- Adsorption on metal electrodes: examples.- Thermodynamics of ideal polarizable interfaces.- Phenomenological treatment of electron-transfer reactions.- Theoretical considerations of electron-transfer reactions.- The semiconductor-electrolyte interface.- Selected experimental results for electron-transfer reactions.- Inner sphere and ion-transfer reactions.- Hydrogen reaction and electrocatalysis.- Metal deposition and dissolution.- Electrochemical surface processes.- Complex reactions.- Liquid?liquid interfaces.- Experimental techniques for electrode kinetics - non-stationary methods.- Convection techniques.

Elizabeth Santos studied physical chemistry at the University of Córdoba, Argentina, where she received her PhD in Physical Chemistry in 1982. After completing her degree she received a postdoctoral Fellowship from the Deutsche Akademische Austauschdienst (DAAD) to carry out research work at the University of Bonn, in Professor Wolf Vielstich's working group. There she developed new techniques to study the kinetics of fast electron transfer reactions in electrochemistry, and collaborated in the first stages of the development of a new experimental method of line mass spectrometry applied to electrocatalysis. She returned to Argentina in 1987 and became Assistant Professor at the University of Córdoba. Between 1996 and 1998, she was in the Argentina Research Program Integrated Expertises of the International Centre of Migration, Federal Ministerial of Cooperation and Development of Germany. She has visited various research institutions in Europe and the USA. She was a Research Associate in analytical chemistry at the University of Utah and member of the scientific staff at the Centre for Solar Energy and Hydrogen Research in Ulm, Germany. She received the Award of the Secretary of Science and Technology of Córdoba for Academic Excellence in 1991. In 1993, she joined Professor Schmickler's working group in Ulm, where she currently directs the experimental work. She is also an Independent Researcher for the National Council of Scientific Research and Technology (Argentina).Wolfgang Schmickler studied physics and chemistry at the Universities of Bonn and Heidelberg and at the Imperial College in London. In 1973 he received his PhD in Physical Chemistry from the University of Bonn. After completing his degree he received first a Liebig Fellowship from the German Association of the Chemical Industry and then a Heisenberg Fellowship from the German Reseach Foundation (DFG). He used the freedom that these fellowships offered him for extended visits at the FrumkinInstitute