Molecular Conformation and Organic Photochemistry
Time-resolved Photoionization Studies
(Sprache: Englisch)
This outstanding thesis charts the links between a molecule's shape and its photochemical reactivity, which has highly truncated excited states radically different to those in ground-state chemistry. Its novel use of bichromophoric interactions is promising.
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This outstanding thesis charts the links between a molecule's shape and its photochemical reactivity, which has highly truncated excited states radically different to those in ground-state chemistry. Its novel use of bichromophoric interactions is promising.
Klappentext zu „Molecular Conformation and Organic Photochemistry “
Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecules relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furhtermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.
Inhaltsverzeichnis zu „Molecular Conformation and Organic Photochemistry “
Aspects and investigation of photochemical dynamics.- A time-resolved probing method: photoionization.- Simulation of time-resolved photoionization signals.- Simulation: the Norrish type-I reaction in acetone.- Experimental setups.- Paracyclophanes I: [2+2]cycloaddition of ethylenes.- Paracyclophanes II: The Paternò-Büchi reaction.- Probing structural dynamics by interaction between chromophores.
Bibliographische Angaben
- Autor: Rasmus Y. Brogaard
- 2012, 2012, XVI, 124 Seiten, Maße: 16 x 24,1 cm, Gebunden, Englisch
- Verlag: Springer, Berlin
- ISBN-10: 3642293808
- ISBN-13: 9783642293801
- Erscheinungsdatum: 18.05.2012
Sprache:
Englisch
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