The Notion of Activity in Chemistry
(Sprache: Englisch)
This book provides deep insight into the physical quantity known as chemical activity. The author probes deep into classical thermodynamics in Part I, and then into statistical thermodynamics in Part II, to provide the necessary background. The treatment...
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Klappentext zu „The Notion of Activity in Chemistry “
This book provides deep insight into the physical quantity known as chemical activity. The author probes deep into classical thermodynamics in Part I, and then into statistical thermodynamics in Part II, to provide the necessary background. The treatment has been streamlined by placing some background material in appendices. Chemical Activity is of interest not only to those in chemical thermodynamics, but also to chemical engineers working with mass transfer and its applications - for example, separation methods.
Inhaltsverzeichnis zu „The Notion of Activity in Chemistry “
1st part: The Activity in Classical Thermodynamics Chapter 1: Thermodynamic systemsChapter 2: Gibbs and Helmhotz energiesChapter 3: Escaping tendency and molar Gibbs energyChapter 4 : Partial molar propertiesChapter 5: Chemical potential or partial molar Gibbs energyChapter 6: An overview of the notion of activityChapter 7: The concept of fugacityChapter 8: Ideal solutionsChapter 9: Definitions of the activityChapter 10: Activity of a gazChapter 11: Activities of non- electrolytes in solutionsChapter 12:Activities of electrolytes: definitions Chapter 13: Determination of the activity of non-electrolytesChapter 14: Determination of the activity of electrolytesChapter 15: Debye and Hückel 's relationsChapter 16: Excess Gibbs energies and activitiesChapter 17: Chemical equilibrium constants : activities and Gibbs energies of reactionsChapter 18: Derivation of thermodynamic equilibrium constants- pH and its measureChapter 19: General principles of calculations of ionic species concentrations in solutions involving activities 2nd part: The Activity in Statistical Thermodynamics Chapter 20: Statistical thermodynamics in briefChapter 21: Concept of ensembles and postulatesChapter 22: The canonical ensemble: notion of distributionChapter 23: Thermodynamic quantities in the framework of the canonical ensembleChapter 24: Other ensembles Chapter 25: Systems of molecules and subsystems independent distinguishable and "indistinguishable" Chapter 26: Perfect gases Chapter 27: Classical statistical mechanics- Notion of configuration - Classical canonical partition function <Chapter 28: The configurational partition function - Molecular distribution functions Chapter 29: The radial distribution function Chapter 30: Radial distribution function and thermodynamic quantities- calculations of the internal energy and of the pressure of a system Chapter 31: Radial distribution function and calculation of the isothermal compressibility coefficient of a system Chapter 32: The chemical
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potential and the radial distribution function . General formal introduction of the activity and of the activity coefficient Chapter 33: Imperfect gases - The virial coefficients in terms of interaction potential energies Chapter 34: A statistical expression of the activity. A relation between it and the concentration in the case of an imperfect gaz Chapter 35: Activities of gases in a mixture of imperfect gasesChapter 36: Chemical equilibria between gases and statistical thermodynamicsChapter 37: Activity coefficients of gasesChapter 38: Activities and concentrations of non-electrolytes in dilute liquid solutions - McMillan- Mayer's theory of their osmotic pressureChapter 39: A study of dilute solutions of non-electrolytes at constant pressure and temperatureChapter 40: The activity coefficients of solutes in binary non-electrolyte solutionsChapter 41: Molecular distribution functions in binary mixturesChapter 42: The Kirkwood-Buff's theory- Changes of chemical potentials of solutes with their concentrations at constant pressure and temperature Chapter 43: Expressions of the chemical potentials of the components of ideal solutions of non- electrolytes Chapter 44: Chemical potentials, activities and activity coefficients of the components of a non- ideal solution of a non-electrolyte Chapter 45: Expressions of the activities of non-electrolytes and of their coefficientsChapter 46: More on the Debye-Hückel 's theoryChapter 47: Distribution functions and the theory of electrolytes solutionsChapter 48: The activity notion in retrospect. AppendicesAbout Some AuthorsBibliography
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Autoren-Porträt von Jean-Louis Burgot
Jean-Louis Burgot is a retired Professor of analytical chemistry in Rennes, France.
Bibliographische Angaben
- Autor: Jean-Louis Burgot
- 2016, 1st ed. 2017, XLI, 608 Seiten, Maße: 16 x 24,1 cm, Gebunden, Englisch
- Verlag: Springer, Berlin
- ISBN-10: 3319463993
- ISBN-13: 9783319463995
- Erscheinungsdatum: 03.01.2017
Sprache:
Englisch
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