Modern Gold Catalyzed Synthesis (ePub)

GOLD-CATALYZED ADDITION OF HETEROATOM NUCLEOPHILES TO ALKYNES Gold-Alkyne Complexes Hydrochlorination Hydration Hydroalkoxylation Hydroamination Hydrothiloation Cyclization to Aromatic Heterocycles GOLD-CATALYZED ADDITIONS TO ALLENES Gold-Allene Complexes O-Nucleophiles N-Nucleophiles S-Nucleophiles GOLD-CATALYZED ADDITIONS TO ALKENES Gold-Alkene Complexes O-Nucleophiles N-Nucleophiles GOLD-CATALYZED BENZANNULATIONS GOLD-CATALYZED CYCLOISOMERIZATION AND REARRANGEMENT REACTIONS Enyne Cyclization and Related Cycloisomerizations Rearrangement of Propargyl Esters, Amides and Related Substrates Sigmatropic Rearrangements GOLD-CATALYZED OXIDATION REACTIONS Oxidation of Alkenes Oxidation of Alcohols GOLD-CATALYZED REDUCTION REACTIONS Hydrogenation of C-C Multiple Bonds Reduction of C-O Double Bonds Reduction of Nitro Compounds GOLD-CATALYZED ALDOL AND RELATED REACTIONS Aldol Reactions Mannich Reactions Michael Additions APPLICATION OF GOLD-CATALYZED REACTIONS TO NATURAL PRODUCT SYNTHESIS

Stephen Hashmi is professor for Organic Chemistry at University of Heidelberg, Germany. He obtained his academic degrees from Ludwig-Maximilians-Universität München, after his postdoctoral studies with Barry M. Trost at Stanford University he started his Habilitation at Freie Universität Berlin with Johann Mulzer. During that time he followed Prof. Mulzer to Johann Wolfgang Goethe-Universität Franfurt and Universität Wien. He then returned to Frankfurt to finish his Habilitation. After the stations at University of Tasmania, Australia, Universität Marburg, and Universität Stuttgart, he was appointed a full professorship at Heidelberg University, where he is also involved in the Catalysis Research Laboratory (CaRLa). He received a number of awards, including a Karl-Zieger fellowship, the ORCHEM prize for natural scientists and the Hector research award.

F. Dean Toste was born in Terceira, Azores, Portugal but soon moved to Toronto Canada. He received his B.Sc. and M.Sc. degrees in chemistry from the University of Toronto, Canada where he worked with Prof. Ian W. J. Still. In 1995, he began his doctoral studies at Stanford
University under the direction of Professor Barry M. Trost. Following postdoctoral studies with Professor Robert H. Grubbs at Caltech, he joined the faculty at the University of California, Berkeley in 2002, and was promoted to Associate Professor in 2006 and Professor in 2009.
Professor Toste?s honors include an Alfred P. Sloan Research Fellowship, the Cope Scholar Award and the E. J. Corey Award from the American Chemical Society, BASF Catalysis Award, the OMCOS and Thieme Award from IUPAC, the Merck Award from the Royal Society of
Chemistry, the Mukaiyama Award, the Tetrahedron Young Investigator Award and numerous awards from the pharmaceutical industry.

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